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Journal article
The Synthesis and Characterization of Highly Fluorescent Polycyclic Azaborine Chromophorese
Journal of organic chemistry, Vol.81(22), pp.10955-10963
11/18/2016
PMID: 27704820
Web of Science ID: WOS:000391248800033
Abstract
Six new heteroaromatic polycyclic azaborine chromophores were designed, synthesized, and investigated as easily tunable high-luminescent organic materials. The impact of the nitrogen-boron-hydroxy (N-BOH) unit in the azaborines was investigated by comparison with their N-carbonyl analogs. Insertion of the N-B(OH)-C unit into heteroaromatic polycyclic compounds resulted in strong visible absorption and sharp fluorescence with efficient quantum yields. The solid-state fluorescence of the heteroaromatic polycyclic compounds displayed a large Stokes shift compared to being in solution. The large Stokes shifts observed offset the self-quench effect in the solid state.
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Details
- Title
- The Synthesis and Characterization of Highly Fluorescent Polycyclic Azaborine Chromophorese
- Publication Details
- Journal of organic chemistry, Vol.81(22), pp.10955-10963
- Resource Type
- Journal article
- Publisher
- American Chemical Society
- Copyright
- © 2016 American Chemical Society
- Identifiers
- WOS:000391248800033; 99380176197206600
- Academic Unit
- Chemistry; Hal Marcus College of Science and Engineering
- Language
- English