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Journal article
Studies in Acyl C-H Activation via Aryl and Alkyl to Acyl "Through Space" Migration of Palladium
Organic letters, Vol.11(12), pp.2591-2593
06/18/2009
PMID: 19445501
Web of Science ID: WOS:000266930900029
Abstract
Examples of the 1,4-migration of a palladium moiety in aryl- and alkylpalladium intermediates to the acyl position of an aldehyde or formamide have been observed. The resulting acylpalladium intermediate can undergo ester or carbamate formation by reaction with an alcohol; decarbonylation, followed by beta hydride elimination to an alkene; reaction with an organomercurial to form an ester; or alkene insertion. Deuterium-labeling studies have been used to confirm the palladium migration mechanism.
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Details
- Title
- Studies in Acyl C-H Activation via Aryl and Alkyl to Acyl "Through Space" Migration of Palladium
- Publication Details
- Organic letters, Vol.11(12), pp.2591-2593
- Resource Type
- Journal article
- Publisher
- American Chemical Society (ACS)
- Number of pages
- 3
- Grant note
- National Science Foundation; National Science Foundation (NSF) Johnson Matthey, Inc. Kawaken Fine Chemicals Co., Ltd. Department of Science and Technology, Government of India; Department of Science & Technology (India)
- Copyright
- Copyright © 2009 American Chemical Society
- Identifiers
- WOS:000266930900029; 99380482397206600
- Academic Unit
- Chemistry; Hal Marcus College of Science and Engineering
- Language
- English