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Journal article
ChemInform Abstract: Benzylic C-H Activation and C-O Bond Formation via Aryl to Benzylic 1,4-Palladium Migrations
ChemInform: Selected abstracts in chemistry, Vol.39(43), 101
10/21/2008
Abstract
Trapping of benzylic palladium intermediates [generated by aryl to benzyl migration in methylarene derivatives (I) or (VI)] with carboxylates (II) or phenoxide (IV) provides access to the corresponding benzylic esters (III), (VII) or ethers (V) in moderate yields. Under the same reaction conditions, the oxidation of hydroxymethylnaphthalene derivatives (VIII) is smoothly achieved to give the corresponding ketones (IX). The reaction mechanism is discussed in detail.
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- Title
- ChemInform Abstract: Benzylic C-H Activation and C-O Bond Formation via Aryl to Benzylic 1,4-Palladium Migrations
- Publication Details
- ChemInform: Selected abstracts in chemistry, Vol.39(43), 101
- Resource Type
- Journal article
- Publisher
- Wiley-VCH Verlag GmbH & Co. KGaA; Germany
- Number of pages
- 1
- Copyright
- Copyright © 2008 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
- Identifiers
- 99380480796606600
- Academic Unit
- Hal Marcus College of Science and Engineering ; Chemistry
- Language
- English